DSC Study on Micro-phase Separation of RIM Polyurethane Urea- Effect of Hard Segment Structure and Content on Micro-phase Separation
1.Experimental part 1.1 Raw material Ammonia ester modified liquefied MDI (U-MDI ), NCO%=28.4 %, functionality 2, ethylene oxide terminated polypropylene oxide polyether (PPO), ZS-2185, Mn=2000, [K+]<5ppm, primary hydroxyl content>70% in DETDA, 2,4-isomer/2,6-isomer=80/20. MDA and catalyst dibutyltin dilaurate are chemical reagents, catalyst dosage: 2.0×10-1g cat./g PPO. 1.2 Sample preparation The raw materials are kept at 40 ℃. PPO, diamine chain extender and catalyst (component a) and u-MDI (component b) are mixed by 200g in a 50ml plastic beaker and poured into a mold with a Beder stirrer (1600r/min), the materials react quickly in the mold and are molded, the samples are taken out after 1-2 mins, the post-curing conditions are 120 ℃/30 min, and then maintained at 60℃ for 7 days. 1.3 DSC test Du Pont 1090 thermal analyzer and its matching thermal analysis crucible was heated at -120~250℃ and temperature raise at 20℃/min in N2 atmosphere, and ...