Silicon nitride Si3N4 is a non-oxide high temperature ceramic structural material. Powdered Si3N4 can be prepared by reacting a mixture of SiCl4 vapor and NH3 gas. Powdered Si3N4 is unstable to air and water. Powdered Si3N4 can form a pungent odor, a gas commonly used as a refrigerant and a poorly soluble acid when it is in contact with water. Powdered Si3N4 can generate N2 and contact with air. a substance. However, heat treatment of powdered Si3N4 and appropriate amount of MgO (refractory) in a closed vessel at 230 ° C, 1.01 × 105 Pa and 185 ° C, can obtain a solid material with a very tight structure and relatively stable air and water. (1) Write the reaction equation for the preparation of Si3N4 from SiCl4 and NH3: ______. The mixture of vapor of SiCl4 and NH3 reacts to form Si3N4, and its chemical equation is: 3SiCl4+4NH3═Si3N4+12HCl; so the answer is: 3SiCl4+4NH3═Si3N4+12HCl; (2) Write the equation for the reaction of powdered Si3N4 and H2O and O2 respectively...
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